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Some cyclic tetra-amine complexes of palladium(II) and ruthenium(III)

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dc.contributor.authorRenfrew, Richard William
dc.date.accessioned2011-03-16T22:32:23Z
dc.date.accessioned2022-10-25T05:42:51Z
dc.date.available2011-03-16T22:32:23Z
dc.date.available2022-10-25T05:42:51Z
dc.date.copyright1975
dc.date.issued1975
dc.description.abstractFour configurational isomers of both (C-meso) and (C-racemic) 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetra-azacyclotetradecane palladium(II) conveniently characterised by infra-red and proton magnetic resonance spectroscopy are reported. Configurations and conformations of the five and six-membered chelate rings were determined and compared with the analogous square planar nickel(II) complexes. The influence of anions such as ClO4-, ZnCl4 2-, NCS-, NO3-, I-, Cl- on the configurations adopted has also been investigated. A wide range of synthetic methods for a ruthenium(III) analogue of the palladium(II) cyclic tetra-amine complexes were attempted, but without success.en_NZ
dc.formatpdfen_NZ
dc.identifier.urihttps://ir.wgtn.ac.nz/handle/123456789/23324
dc.languageen_NZ
dc.language.isoen_NZ
dc.publisherTe Herenga Waka—Victoria University of Wellingtonen_NZ
dc.rights.holderAll rights, except those explicitly waived, are held by the Authoren_NZ
dc.rights.licenseAuthor Retains Copyrighten_NZ
dc.rights.urihttps://www.wgtn.ac.nz/library/about-us/policies-and-strategies/copyright-for-the-researcharchive
dc.subjectTertra-aminesen_NZ
dc.subjectPalladiumen_NZ
dc.subjectRutheniumen_NZ
dc.subjectChemistryen_NZ
dc.titleSome cyclic tetra-amine complexes of palladium(II) and ruthenium(III)en_NZ
dc.typeTexten_NZ
thesis.degree.disciplineChemistryen_NZ
thesis.degree.grantorTe Herenga Waka—Victoria University of Wellingtonen_NZ
thesis.degree.levelMastersen_NZ
thesis.degree.nameMaster of Scienceen_NZ
vuwschema.type.vuwAwarded Research Masters Thesisen_NZ

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