dc.contributor.author |
Tan, Ching Chee |
|
dc.date.accessioned |
2011-03-16T22:32:40Z |
|
dc.date.accessioned |
2022-10-25T05:44:11Z |
|
dc.date.available |
2011-03-16T22:32:40Z |
|
dc.date.available |
2022-10-25T05:44:11Z |
|
dc.date.copyright |
1975 |
|
dc.date.issued |
1975 |
|
dc.identifier.uri |
https://ir.wgtn.ac.nz/handle/123456789/23327 |
|
dc.description.abstract |
Synthetic peptide-like ligands N,N'-bis-(1,2 aminoethyl)-malondiamide, N,N-bis-(1,2 aminopropyl)malondiamide and their nickel(II) complexes (NiH-2AEM and NiH-2 1,2 APM) are prepared and characterised.
The rates of the substitution reaction of these complexes with ethylenediamine and ethylenediamine tetracetic acid (EDTA) were studied from pH 7.50 to 12.00 at 25°C and ionic strength = 1 Using the stopped flow technique and conventional photometric method. The rate constants are obtained.
A mechanism based on the kinetic results obtained is proposed. |
en_NZ |
dc.format |
pdf |
en_NZ |
dc.language |
en_NZ |
|
dc.language.iso |
en_NZ |
|
dc.publisher |
Te Herenga Waka—Victoria University of Wellington |
en_NZ |
dc.title |
Substitution reactions of some square planer nickel(II) complexes |
en_NZ |
dc.type |
Text |
en_NZ |
vuwschema.type.vuw |
Awarded Research Masters Thesis |
en_NZ |
thesis.degree.discipline |
Chemistry |
en_NZ |
thesis.degree.grantor |
Te Herenga Waka—Victoria University of Wellington |
en_NZ |
thesis.degree.level |
Masters |
en_NZ |
thesis.degree.name |
Master of Science |
en_NZ |