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Acid catalysed isomerisations in the hexyne-hexadiene system

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dc.contributor.authorBeale, William John
dc.date.accessioned2011-03-16T22:33:19Z
dc.date.accessioned2022-10-25T05:47:46Z
dc.date.available2011-03-16T22:33:19Z
dc.date.available2022-10-25T05:47:46Z
dc.date.copyright1970
dc.date.issued1970
dc.description.abstractAcid catalysed isomerisations in the hexyne-hexadiene system (1-hexyne, 2-hexyne, 3-hexyne, 1,2-hexadiene and 2,3-hexadiene) have been studied. Isomerisation, in solutions of tetrafluoroboric acid in sulpholane, occurs rapidly and all evidence favours a hexyne-hexadiene-hexyne pathway, with carbonium ion intermediates. No conjugated dienes were detected in products of isomerisation. Equilibration of the isomers could not be achieved due to irreversible addition reactions which produced 2,2 and 3,3-difluorohexane.en_NZ
dc.formatpdfen_NZ
dc.identifier.urihttps://ir.wgtn.ac.nz/handle/123456789/23335
dc.languageen_NZ
dc.language.isoen_NZ
dc.publisherTe Herenga Waka—Victoria University of Wellingtonen_NZ
dc.rights.holderAll rights, except those explicitly waived, are held by the Authoren_NZ
dc.rights.licenseAuthor Retains Copyrighten_NZ
dc.rights.urihttps://www.wgtn.ac.nz/library/about-us/policies-and-strategies/copyright-for-the-researcharchive
dc.subjectIsomerismen_NZ
dc.subjectCatalysisen_NZ
dc.titleAcid catalysed isomerisations in the hexyne-hexadiene systemen_NZ
dc.typeTexten_NZ
thesis.degree.disciplineChemistryen_NZ
thesis.degree.grantorTe Herenga Waka—Victoria University of Wellingtonen_NZ
thesis.degree.levelMastersen_NZ
thesis.degree.nameMaster of Scienceen_NZ
vuwschema.type.vuwAwarded Research Masters Thesisen_NZ

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