Spectrophotometric studies of reaction rates under high pressure
| dc.contributor.author | Vickerman, Philippa Anne | |
| dc.date.accessioned | 2011-03-16T22:38:40Z | |
| dc.date.accessioned | 2022-10-25T06:13:22Z | |
| dc.date.available | 2011-03-16T22:38:40Z | |
| dc.date.available | 2022-10-25T06:13:22Z | |
| dc.date.copyright | 1973 | |
| dc.date.issued | 1973 | |
| dc.description.abstract | Activation volumes for the aquation of dichloro-bisethylene diamine cobalt(III) ion and the bromate-iodide reaction were measured using a spectrophotometric technique. Values of ΔV* were +5 ± 2 cm3 mol-1 and -3 ±1cm3 mol-1 respectively. The positive value of ΔV* obtained for the aquation reaction and also its independence of pressure supports the suggestion that the mechanism is a dissociative controlled process. This agrees with previous observations. The small negative value of ΔV* obtained for the bromate-iodide reaction is discussed in terms of a neutralisation mechanism using a previous model. It is also compared with the related bromate-bromide reaction. | en_NZ |
| dc.format | en_NZ | |
| dc.identifier.uri | https://ir.wgtn.ac.nz/handle/123456789/23392 | |
| dc.language | en_NZ | |
| dc.language.iso | en_NZ | |
| dc.publisher | Te Herenga Waka—Victoria University of Wellington | en_NZ |
| dc.subject | Chemical kinetics | en_NZ |
| dc.subject | Spectrophotometry | en_NZ |
| dc.title | Spectrophotometric studies of reaction rates under high pressure | en_NZ |
| dc.type | Text | en_NZ |
| thesis.degree.discipline | Chemistry | en_NZ |
| thesis.degree.grantor | Te Herenga Waka—Victoria University of Wellington | en_NZ |
| thesis.degree.level | Masters | en_NZ |
| vuwschema.type.vuw | Awarded Research Masters Thesis | en_NZ |
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