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Acid catalysed acetylene-allene isomerisations

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dc.contributor.authorHei, Siang-King
dc.date.accessioned2011-03-10T22:53:46Z
dc.date.accessioned2022-10-25T04:40:09Z
dc.date.available2011-03-10T22:53:46Z
dc.date.available2022-10-25T04:40:09Z
dc.date.copyright1969
dc.date.issued1969
dc.description.abstractThe isomerisation of l-hexyne, 2-hexyne, 3-hexyne, 1,2-hexadiene and 2,3-hexadiene have been studied in solutions of sulphuric acid in sulpholane. The probable mechanism of the isomerisations involving carbonium ions has been outlined. There appears to be no rearrangement of the intermediate carbonium ions involving hydride ion shifts. Free energy changes in the isomerisation were not determined, since equilibration studies could not be carried out due to side reactions during the isomerisations.en_NZ
dc.formatpdfen_NZ
dc.identifier.urihttps://ir.wgtn.ac.nz/handle/123456789/23184
dc.languageen_NZ
dc.language.isoen_NZ
dc.publisherTe Herenga Waka—Victoria University of Wellingtonen_NZ
dc.rights.holderAll rights, except those explicitly waived, are held by the Authoren_NZ
dc.rights.licenseAuthor Retains Copyrighten_NZ
dc.rights.urihttps://www.wgtn.ac.nz/library/about-us/policies-and-strategies/copyright-for-the-researcharchive
dc.subjectIsomerismen_NZ
dc.titleAcid catalysed acetylene-allene isomerisationsen_NZ
dc.typeTexten_NZ
thesis.degree.disciplineChemistryen_NZ
thesis.degree.grantorTe Herenga Waka—Victoria University of Wellingtonen_NZ
thesis.degree.levelMastersen_NZ
thesis.degree.nameMaster of Scienceen_NZ
vuwschema.type.vuwAwarded Research Masters Thesisen_NZ

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