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The Supposed trithiocyanate of iodine

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dc.contributor.authorDavies, Janet Raby
dc.date.accessioned2010-11-23T00:18:34Z
dc.date.accessioned2022-10-25T00:29:29Z
dc.date.available2010-11-23T00:18:34Z
dc.date.available2022-10-25T00:29:29Z
dc.date.copyright1962
dc.date.issued1962
dc.description.abstractThe preparation of "iodine trithiocyanate" and "iodine tricyanate" were reported, in 1938, by reaction of iodine monochloride with potassium thiocyanate and with potassium cyanate respectively. The properties given, in particular the lack of volatility and solubility and the stability to water are different from those normally observed in tervalent iodine compounds. This suggested polymerized compounds of the form [I(SCN)3,]n and [I(CNO)3]n. As the (SCN) group can act as a bridge, X-SCN-Y, it was thought polymerization might arise in this way. Similarly polymerization of iodine tricyanate may be possible through X-OCN-Y bridges. Work was undertaken to investigate the structures of these compounds.en_NZ
dc.formatpdfen_NZ
dc.identifier.urihttps://ir.wgtn.ac.nz/handle/123456789/22672
dc.languageen_NZ
dc.language.isoen_NZ
dc.publisherTe Herenga Waka—Victoria University of Wellingtonen_NZ
dc.rights.holderAll rights, except those explicitly waived, are held by the Authoren_NZ
dc.rights.licenseAuthor Retains Copyrighten_NZ
dc.rights.urihttps://www.wgtn.ac.nz/library/about-us/policies-and-strategies/copyright-for-the-researcharchive
dc.subjectTrithiocyanateen_NZ
dc.subjectIodineen_NZ
dc.subjectChemistryen_NZ
dc.titleThe Supposed trithiocyanate of iodineen_NZ
dc.typeTexten_NZ
thesis.degree.disciplineChemistryen_NZ
thesis.degree.grantorTe Herenga Waka—Victoria University of Wellingtonen_NZ
thesis.degree.levelMastersen_NZ
thesis.degree.nameMaster of Scienceen_NZ
vuwschema.type.vuwAwarded Research Masters Thesisen_NZ

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