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Kinetic studies of the hydrolysis of sulphate esters

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dc.contributor.authorEdmonds, John Arthur Gerard
dc.date.accessioned2011-03-16T23:42:00Z
dc.date.accessioned2022-10-25T06:23:10Z
dc.date.available2011-03-16T23:42:00Z
dc.date.available2022-10-25T06:23:10Z
dc.date.copyright1969
dc.date.issued1969
dc.description.abstractRecently there has been considerable interest in the acid catalysed hydrolysis of arylsulphate esters. It has been shown that unlike the hydrolysis of aryl selenates the reaction probably proceeds by an A-1 mechanism. Nucleophilic catalysis by amines has been observed in the hydrolysis of p-nitrophenyl sulphate and intramolecular carboxyl group catalysis occurs with salicyl sulphate as with salicyl phosphate. The object of this study was to investigate the catalytic effects of acid and of metal ions on sulphate esters.en_NZ
dc.formatpdfen_NZ
dc.identifier.urihttps://ir.wgtn.ac.nz/handle/123456789/23414
dc.languageen_NZ
dc.language.isoen_NZ
dc.publisherTe Herenga Waka—Victoria University of Wellingtonen_NZ
dc.rights.holderAll rights, except those explicitly waived, are held by the Authoren_NZ
dc.rights.licenseAuthor Retains Copyrighten_NZ
dc.rights.urihttps://www.wgtn.ac.nz/library/about-us/policies-and-strategies/copyright-for-the-researcharchive
dc.subjectEstersen_NZ
dc.subjectHydrolysisen_NZ
dc.subjectSulfatesen_NZ
dc.subjectChemistryen_NZ
dc.titleKinetic studies of the hydrolysis of sulphate estersen_NZ
dc.typeTexten_NZ
thesis.degree.disciplineChemistryen_NZ
thesis.degree.grantorTe Herenga Waka—Victoria University of Wellingtonen_NZ
thesis.degree.levelMastersen_NZ
thesis.degree.nameMaster of Scienceen_NZ
vuwschema.type.vuwAwarded Research Masters Thesisen_NZ

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