dc.contributor.author |
Harrison, Silvana Angela Rosanna |
|
dc.date.accessioned |
2011-03-16T22:32:09Z |
|
dc.date.accessioned |
2022-10-25T05:41:58Z |
|
dc.date.available |
2011-03-16T22:32:09Z |
|
dc.date.available |
2022-10-25T05:41:58Z |
|
dc.date.copyright |
1976 |
|
dc.date.issued |
1976 |
|
dc.identifier.uri |
https://ir.wgtn.ac.nz/handle/123456789/23322 |
|
dc.description.abstract |
Several aspects of cyclopropa-arene chemistry have been examined.
In the first part of this work the decomposition of phenanthraquinone 4-phenyl-3-(phenylimino)semicarbazone and phenanthraquinone 4-p-tolyl-3-(p-tolylimino) semicarbazone failed to yield the appropriate 1-(arylimino) cyclopropa[1] - phenanthrene as reported in the literature. Instead the phenanthraquinone 4-arylsemicarbazones were obtained and their structure confirmed by independent synthesis.
An attempt to synthesize cyclopropa[a]naphthalene via a 1,3-elimination route was undertaken in the second part of the work. However the treatment of 1-bromo-2-methoxymethylnaphthalene with n-butyl lithium resulted in the formation of 2-(1'-methoxy) pentylnaphthalene and 2-methoxymethylnaphthalene. |
en_NZ |
dc.format |
pdf |
en_NZ |
dc.language |
en_NZ |
|
dc.language.iso |
en_NZ |
|
dc.publisher |
Te Herenga Waka—Victoria University of Wellington |
en_NZ |
dc.title |
Some aspects of cyclopropa-arene chemistry I. Iminocyclopropa[1]phenanthrenes II. Cyclopropa[a]naphthalene |
en_NZ |
dc.type |
Text |
en_NZ |
vuwschema.type.vuw |
Awarded Research Masters Thesis |
en_NZ |
thesis.degree.discipline |
Chemistry |
en_NZ |
thesis.degree.grantor |
Te Herenga Waka—Victoria University of Wellington |
en_NZ |
thesis.degree.level |
Masters |
en_NZ |
thesis.degree.name |
Master of Science |
en_NZ |