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Acid catalysed acetylene-allene isomerisations

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dc.contributor.author Hei, Siang-King
dc.date.accessioned 2011-03-10T22:53:46Z
dc.date.accessioned 2022-10-25T04:40:09Z
dc.date.available 2011-03-10T22:53:46Z
dc.date.available 2022-10-25T04:40:09Z
dc.date.copyright 1969
dc.date.issued 1969
dc.identifier.uri https://ir.wgtn.ac.nz/handle/123456789/23184
dc.description.abstract The isomerisation of l-hexyne, 2-hexyne, 3-hexyne, 1,2-hexadiene and 2,3-hexadiene have been studied in solutions of sulphuric acid in sulpholane. The probable mechanism of the isomerisations involving carbonium ions has been outlined. There appears to be no rearrangement of the intermediate carbonium ions involving hydride ion shifts. Free energy changes in the isomerisation were not determined, since equilibration studies could not be carried out due to side reactions during the isomerisations. en_NZ
dc.format pdf en_NZ
dc.language en_NZ
dc.language.iso en_NZ
dc.publisher Te Herenga Waka—Victoria University of Wellington en_NZ
dc.subject Isomerism en_NZ
dc.title Acid catalysed acetylene-allene isomerisations en_NZ
dc.type Text en_NZ
vuwschema.type.vuw Awarded Research Masters Thesis en_NZ
thesis.degree.grantor Te Herenga Waka—Victoria University of Wellington en_NZ
thesis.degree.level Masters en_NZ


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